2010
DOI: 10.1016/j.inoche.2010.07.012
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Synthesis, crystal structures, and biological activities of 2-thiophene N(4)-methylthiosemicarbazone and its unusual hexanuclear silver(I) cluster

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Cited by 32 publications
(8 citation statements)
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“…Além disso, as tiossemicarbazonas constituem uma classe orgânica reconhecida por possuir significativa deslocalização eletrônica. Em consequência disso, tais compostos podem apresentar-se em equilíbrio tautomérico nas formas tiona (C=S) ou tiol (C-SH), gerando duas configurações Z ou E, podendo haver predominância ou existência exclusiva de apenas uma destas formas (LI et al 2010).…”
Section: Compostos Tiossemicarbazonasunclassified
“…Além disso, as tiossemicarbazonas constituem uma classe orgânica reconhecida por possuir significativa deslocalização eletrônica. Em consequência disso, tais compostos podem apresentar-se em equilíbrio tautomérico nas formas tiona (C=S) ou tiol (C-SH), gerando duas configurações Z ou E, podendo haver predominância ou existência exclusiva de apenas uma destas formas (LI et al 2010).…”
Section: Compostos Tiossemicarbazonasunclassified
“…1, as reference (Li, Zhang, Zhang, & Niu, 2010) described. The products were purified by recrystallization from ethanol detected by HPLC as one peak and identified by ESI-MS and 1 H NMR analyses.…”
Section: Synthesismentioning
confidence: 99%
“…[3,4,9,16,19,20] The results have revealed that heterocyclic thiosemicarbazones and their metal complexes show significant biological activities. After a careful literature search, we can affirm that thiophene-2-carbaldehyde N(4)-substituted thiosemicarbazones and their diorganotin(IV) complexes are scarce.…”
Section: Synthesis Crystal Structures and Cytotoxicity Of Thiophenementioning
confidence: 99%
“…After a careful literature search, we can affirm that thiophene-2-carbaldehyde N(4)-substituted thiosemicarbazones and their diorganotin(IV) complexes are scarce. [20,21] Therefore, it seemed important for us to fulfill this work.…”
Section: Synthesis Crystal Structures and Cytotoxicity Of Thiophenementioning
confidence: 99%