2019
DOI: 10.1021/acsomega.9b03186
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Synthesis, Kinetic Study, and Spectroscopic Analysis of Peroxidase-like Pinch-Porphyrin Fe(III) Complexes

Abstract: In the present manuscript, we report the kinetic and spectroscopic analysis of six new pinch-porphyrins: protoporphyrin-picpenta 1, mesoporphyrin-picpenta 2, deuteroporphyrin-picpenta 3, protoporphyrin-picocta 4, mesoporphyrin-picocta 5, and deuteroporphyrin-picocta 6. The Michaelis–Menten enzymatic pathway and the guaiacol test confirmed the ability of the compounds to function like new peroxidase models. UV–vis, 1H NMR, and electron spin resonance studies are in accordance with porphyrin-Fe(III) molecules wi… Show more

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