Synthesis of 3-chloropiperidines by iodide-mediated electrolysis

Kirchner, Michael; Dubinina, Yana; Göttlich, Richard

doi:10.1039/d3qo00687e

Org. Chem. Front.

2023

DOI: 10.1039/d3qo00687e

|View full text |Cite

Synthesis of 3-chloropiperidines by iodide-mediated electrolysis

Michael Kirchner,

Yana Dubinina,

Richard Göttlich

Abstract: Herein we report the cyclization of N-pentenylamines and their corresponding hydrochloric acid salts to 3-chloropiperidines under ambient conditions in an electroorganic fashion with tetrabutylammoniumiodide (TBAI) as redox catalyst. Through iodide...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 39 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Electrochemical Selenized Reaction of N-Arylbicyclo[1.1.0]butane-1-carboxamides: Access to 3-(Arylselanyl)spiro[cyclobutane-1,3′-indolin]-2′-one Derivatives

Liu,

Qian,

Zhao

et al. 2024

J. Org. Chem.

View full text Add to dashboard Cite

A novel selenized reaction of N-arylbicyclo [1.1.0]butane-1-carboxamides with diselenide for the synthesis of polycyclic indoline derivatives is developed under electrochemical conditions. The synthesis is achieved by the bicyclo[1.1.0]butane strain-release reaction and intramolecular cyclization process. In addition, this approach features a wide range of substrates, good group tolerance, shorter reaction time, and mild conditions.

show abstract

Electrochemical Selenized Reaction of N-Arylbicyclo[1.1.0]butane-1-carboxamides: Access to 3-(Arylselanyl)spiro[cyclobutane-1,3′-indolin]-2′-one Derivatives

Liu,

Qian,

Zhao

et al. 2024

J. Org. Chem.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis of 3-chloropiperidines by iodide-mediated electrolysis

Abstract: Herein we report the cyclization of N-pentenylamines and their corresponding hydrochloric acid salts to 3-chloropiperidines under ambient conditions in an electroorganic fashion with tetrabutylammoniumiodide (TBAI) as redox catalyst. Through iodide...

Cited by 1 publication

References 39 publications

Electrochemical Selenized Reaction of N-Arylbicyclo[1.1.0]butane-1-carboxamides: Access to 3-(Arylselanyl)spiro[cyclobutane-1,3′-indolin]-2′-one Derivatives

Electrochemical Selenized Reaction of N-Arylbicyclo[1.1.0]butane-1-carboxamides: Access to 3-(Arylselanyl)spiro[cyclobutane-1,3′-indolin]-2′-one Derivatives

Contact Info

Product

Resources

About