Synthesis of 3-R-1,5-dinitro-3-azabicyclo[3.3.1]nonanes fused to azoles

Asadulina, Ekaterina M.; Bastrakov, Maxim A.; Старосотников, А. М.; Качала, В. В.; Шевелев, С. А.

doi:10.1007/s11172-010-0026-2

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Cited by 5 publications

References 13 publications

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Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Thieme

Breit

2014

Angewandte Chemie

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The rhodium-catalyzed, highly N 2 -and N 1 -selective coupling of benzotriazoles with allenes is reported. The exceptionally high N 2 and N 1 selectivities were achieved by using a rhodium(I)/DPEphos and rhodium(I)/JoSPOphos catalyst, respectively. This method permits the atom-economic synthesis of valuable branched N 2 -and N 1 -allylated benzotriazole derivatives and allows for preliminary studies of their reactivity.

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Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Thieme

Breit

2014

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

2014

View full text Add to dashboard Cite

The rhodium-catalyzed, highly N(2) - and N(1) -selective coupling of benzotriazoles with allenes is reported. The exceptionally high N(2) and N(1) selectivities were achieved by using a rhodium(I)/DPEphos and rhodium(I)/JoSPOphos catalyst, respectively. This method permits the atom-economic synthesis of valuable branched N(2) - and N(1) -allylated benzotriazole derivatives and allows for preliminary studies of their reactivity.

show abstract

Double 1,3‐dipolar cycloaddition of N‐methyl Azomethine ylide to meta‐Dinitrobenzene annelated with nitrogen aromatic heterocycles

Bastrakov

Старосотников

Pechenkin

et al. 2010

Journal of Heterocyclic Chem

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Synthesis of 3-R-1,5-dinitro-3-azabicyclo[3.3.1]nonanes fused to azoles

Abstract: 3 R 1,5 Dinitro 3 azabicyclo[3.3.1]nonanes fused to the pyrazole, thiazole, and triazole rings were synthesized by reductive cyclization of meta dinitrobenzazoles.

Cited by 5 publications

References 13 publications

Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Double 1,3‐dipolar cycloaddition of N‐methyl Azomethine ylide to meta‐Dinitrobenzene annelated with nitrogen aromatic heterocycles

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Synthesis of 3-R-1,5-dinitro-3-azabicyclo[3.3.1]nonanes fused to azoles

Abstract: 3 R 1,5 Dinitro 3 azabicyclo[3.3.1]nonanes fused to the pyrazole, thiazole, and triazole rings were synthesized by reductive cyclization of meta dinitrobenzazoles.

Cited by 5 publications

References 13 publications

Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Double 1,3‐dipolar cycloaddition of N‐methyl Azomethine ylide to meta‐Dinitrobenzene annelated with nitrogen aromatic heterocycles

Contact Info

Product

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Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

Unlocking the N² Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes