Synthesis of a diverse set of phosphorus ligands on solid support and their screening in the Heck reaction

Synthesis and characterizations of N,N,N′,N′-tetrakis (diphenylphosphino)ethylendiamine derivatives: Use of palladium(II) complex as pre-catalyst in Suzuki coupling and Heck reactions

“…The improved catalytic activity of transition metal complexes with hemilabile ligands has been extensively reviewed [11][12][13][14]. There has been recently increasing interest in the synthesis of highly active transition metal based catalysts derived from aminophosphines that can be used in different catalytic reactions including allylic alkylation [15][16][17][18], ammination [19][20][21], Heck [22][23][24][25][26][27][28][29][30], Suzuki [31][32][33][34][35], hydroformylation [36][37][38][39] and hydrogenation reactions [40][41][42][43][44]. Palladium containing catalysts serve as straightforward and extremely powerful reagents for the carbon-carbon bond formation [45][46][47].…”

Synthesis and characterization of tris{2-(N,N-bis(diphenylphosphino) aminoethyl} amine derivatives: Application of a palladium(II) complex as a pre-catalyst in the Heck and Suzuki cross-coupling reactions

“…This feature enables the synthesis of a wide range of four membered ring systems containing transition metals such as Cu, Mo, Ni, Pd, Pt and Ru which have potential uses in catalysis [12][13][14]. There has been recently an increasing interest in the synthesis of new and highly active transition metal based catalysts derived from aminophosphines which can be used in different catalytic reactions including allylic alkylation [15][16][17][18], amination [19][20][21], Heck [22][23][24][25][26][27][28], Suzuki [29][30][31][32][33], and hydrogenation reactions [34][35][36][37][38].…”

Phosphines and Related Tervalent Phosphorus Systems

“…411 Mannich reactions between hydroxymethylphosphines and amines have been applied in the synthesis of a variety of new aminomethylphosphines. Included among these are aminomethylphosphine derivatives of adenine, 412 the new unsymmetrical phosphine Ph 2 PCH 2 NHC 6 H 4 PPh 2 , 413 a polymer-bound (N-phosphinoethyl)-aminomethylphosphine, 414 and water-soluble aminomethyl(ferrocenylmethyl)-phosphines. 415 Bis(phosphinomethyl)amino systems have also been described, e.g., (166), 416 the amphiphilic and water-soluble systems (167), 417 and a bis(aminomethylphosphine) derived from 3,4-diaminotoluene.…”