2014
DOI: 10.5012/bkcs.2014.35.9.2803
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Synthesis of a New Cathode Redox Polymer for High Performance in Biofuel Cells

Abstract: High potential and fast electron transfer of a cathode mediator are significant factors for improving the performance of biofuel cells. This paper reports the first synthesis of a cathode redox polymer that is a coordination complex of poly (acrylic acid-vinylpyridine-acryl amide) (PAA-PVP-PAA) and [Os(4,4'-dicarboxylic acid-2,2'-bipyridine)2Cl2] /+ (E o = 0.48 V versus Ag/AgCl). Bilirubin oxidase can be easily incorporated into this polymer matrix, which carried out the four-electron oxygen under typical phys… Show more

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