2024
DOI: 10.1002/macp.202400065
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Synthesis of Aldehyde‐Functionalized Fluorescent Micelles by Self‐Assembly of a Hybrid Polymer Constructed by Hyperbranched Conjugated Polymer Core with Aldehyde End groups and Polyethylene Glycol Shell

Qinglan Tan,
Hui Liang

Abstract: Water‐dispersible fluorescent nano‐/micro‐spheres have been widely used as fluorescent probes in many fields. In this paper, aldehyde‐functionalized fluorescent micelles are synthesized by self‐assembly of end‐modified hyperbranched poly(m‐phenyleneethynylene‐alter‐p‐phenyleneethynylene)(hb‐PMPE). Firstly, hb‐PMPE with ‐Br end‐groups(hb‐PMPE‐Br) is obtained by the polymerization of AB2 monomer PhBr2‐C≡C‐Ph‐C≡CH, then the reaction of hb‐PMPE‐Br with 4‐ethynylbenzaldehyde (EBA) gives end aldehyde‐functionalized … Show more

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