Synthesis of an iron phosphide catalyst based on sulfides and hydrodesulfurization property

Song, Limin; Zhang, Shujuan; Ma, Qing

doi:10.1016/j.cej.2015.06.069

Cited by 21 publications

(13 citation statements)

References 25 publications

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“…In the Fe 2p core level spectra (Figure c), one broad core doublet at 712 and 726 eV is observed, which likely arises from the native (amorphous) oxide formed on the surface of the FeP microspheres . The other two peaks at lower binding energies of 707.5 eV and 720.3 eV can be assigned to Fe 2p 3/2 and Fe 2p 1/2 in FeP, respectively . The P 2p core level spectra (Figure d) of the FeP exhibit two peak regions centered at binding energies of 129.6 eV (2p 3/2 ) and 130.3 eV (P 2p 1/2 ), which can be assigned to low‐valence P in FeP.…”

Section: Resultsmentioning

confidence: 97%

Formation of Uniform FeP Hollow Microspheres Assembled by Nanosheets for Efficient Hydrogen Evolution Reaction

Guo

Feng

et al. 2017

ChemElectroChem

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High‐performance electrocatalysts with superior stability are critically important for their practical applications in the hydrogen evolution reaction (HER). Recently, some electrocatalysts with hollow and porous structures have attracted much attention because of their large surface‐to‐volume ratio and highly exposed active edge sites. In this study, the hierarchical Fe‐based glycolate hollow microspheres composed of nanosheet subunits are synthesized by the solvothermal method. The morphology and microstructure of Fe‐based glycolate hollow microspheres can be controlled by adjusting the amount of ethylenediamine. After phosphorizing in nitrogen, the Fe‐based glycolate can be converted into FeP with well‐retained structure. Furthermore, the hierarchical FeP hollow microspheres have been used as electrocatalysts for HER. Benefitting from its high surface area, the FeP hollow microspheres exhibited high catalytic activity toward HER with low onset overpotential, small Tafel slope, and good stability under acidic conditions. The excellent catalytic activity and long‐term stability suggest promising application potential of FeP hollow microspheres in electrocatalytic hydrogen evolution.

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Section: Resultsmentioning

confidence: 97%

Formation of Uniform FeP Hollow Microspheres Assembled by Nanosheets for Efficient Hydrogen Evolution Reaction

Guo

Feng

et al. 2017

ChemElectroChem

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“…Transition-metal phosphides (TMPs) are a class of newly developed materials with excellent electrocatalytic activity, good electrical conductivity and a plenty of outstanding properties. Thus, they have been extensively studied for applications in water splitting [22,23], hydrodesulfurization [24], and supercapacitor electrodes [25]. Recent research indicates that CoP, Ni 2 P and Cu 3 P [26][27][28] can also be used as efficient electrocatalyst for non-enzymatic H 2 O 2 detection.…”

Section: Introductionmentioning

confidence: 99%

Cobalt Phosphide (Co2P) with Notable Electrocatalytic Activity Designed for Sensitive and Selective Enzymeless Bioanalysis of Hydrogen Peroxide

et al. 2021

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In this work, cobalt phosphide nanoparticles (Co2P NPs) were prepared by simple and mild hydrothermal method without the use of harmful phosphorous source. The morphological structure and surface component of Co2P were characterized by transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy measurements. Considering the excellent electrocatalytic reduction activity and good electrical conductivity of transition-metal phosphide, we fabricated Co2P NPs on indium tin oxide (ITO) substrate (Co2P/ITO) for H2O2 detection. The Co2P/ITO transducer displayed a rapid amperometric response less than 5 s, a broader response range from 0.001 to 10.0 mM and a low detection limit of 0.65 μM. In addition, the non-enzymatic Co2P/ITO sensor showed outstanding selectivity, reproducibility, repeatability and stability, all of which qualified the Co2P/ITO electrode for quite a reliable and promising biosensor for H2O2 sensing.

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“…Recent studies have demonstrated that transitional metal phosphides present better catalytic effects for hydrodesulfurization, hydrodenitrogenation and hydrogenation [22,23]. For instance, Stinner et al fabricated the MoP with better hydrodenitrogenation performance than MoS 2 owing to the enrichment of Mo in MoP [24]; Song et al designed FeP/SiO 2 as hydrodesulfurization catalysts [25]; Ibrahim et al prepared the Ni 0.3 MoP catalysts, supported on Al 2 O 3 as hydrodenitrogenation and hydrodesulfurization catalysts [26]. For the hydrogenation of 4-NP, phosphide materials exhibited remarkably high efficiency.…”

Section: Introductionmentioning

confidence: 99%

Bi-Metal Phosphide NiCoP: An Enhanced Catalyst for the Reduction of 4-Nitrophenol

Sun

et al. 2019

Nanomaterials

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Porous phosphide NixCoyP composite nanomaterials are successfully synthesized at different Ni/Co ratios (=0, 0.5, 1, and 2) to reduce 4-nitrophenol. The X-ray diffraction and X-ray photoelectron spectroscopy results demonstrate that the products are CoP, NiCoP/CoP, NiCoP, and NiCoP/Ni2P when the Ni/Co ratio is 0, 0.5, 1, and 2, respectively. The products exhibit different catalytic performance for reduction of 4-nitrophenol at room temperature. Among them, the pure NiCoP delivers a better catalytic efficiency with kitalicapp=677.4×10−2 min−1 and k=338.7 (Lg−1min−1), due to the synergy between Ni and Co atoms. The sequence of catalytic efficiency of different samples is CoP < NiCoP/CoP < NiCoP/Ni2P < NiCoP.

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Synthesis of an iron phosphide catalyst based on sulfides and hydrodesulfurization property

Cited by 21 publications

References 25 publications

Formation of Uniform FeP Hollow Microspheres Assembled by Nanosheets for Efficient Hydrogen Evolution Reaction

Formation of Uniform FeP Hollow Microspheres Assembled by Nanosheets for Efficient Hydrogen Evolution Reaction

Cobalt Phosphide (Co2P) with Notable Electrocatalytic Activity Designed for Sensitive and Selective Enzymeless Bioanalysis of Hydrogen Peroxide

Bi-Metal Phosphide NiCoP: An Enhanced Catalyst for the Reduction of 4-Nitrophenol

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