Synthesis of arylboronates via the Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates with bis(pinacolato)diboron

Qiu, Di; Li, Songyi; Yue, Guanglu; Mao, Jinshan; Xu, Binduo; Yuan, Xinyu; Ye, Fei

doi:10.1016/j.tetlet.2021.153478

Cited by 3 publications

(1 citation statement)

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“…In 2021, Qiu and Ye reported a desulfitative borylation of sodium arylsulfinates with bis(pinacolato)diboron (Scheme 18b) [81] . Moderate‐to‐good yields of the corresponding aryl boronates were achieved.…”

Section: Palladium‐catalyzed Borylation Reactionmentioning

confidence: 99%

Recent Expedition in Pd‐ and Rh‐Catalyzed C_(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Choy,

Tse,

Kwong

2023

Chemistry An Asian Journal

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Transition metal‐catalyzed borylation has emerged as a powerful and versatile strategy for synthesizing organoboron compounds. These compounds have found widespread applications in various aspects, including organic synthesis, materials science, and medicinal chemistry. This review provides a concise summary of the recent advances in palladium‐ and rhodium‐catalyzed borylation from 2013 to 2023. The review covers the representative examples of catalysts, substrates scope and reaction conditions, with particular emphasis on the development of catalyst systems, such as phosphine ligands, NHC‐carbene, and more. The diverse array of borylative products obtained for further applications in Suzuki‐Miyaura coupling, and other transformations, are also discussed. Future directions in this rapidly evolving field, with the goal of designing more efficient, selective borylation methodologies are highlighted, too.

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Section: Palladium‐catalyzed Borylation Reactionmentioning

confidence: 99%

Recent Expedition in Pd‐ and Rh‐Catalyzed C_(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Choy,

Tse,

Kwong

2023

Chemistry An Asian Journal

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Efficient system for facile access to ortho-substituted aryl boronates through palladium-catalysed borylation

Lamola

Moshapo

Holzapfel

et al. 2023

Tetrahedron Letters

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Recent Advances in the Synthesis of Arylstannanes

Yue¹,

Wei²,

Qiu³

et al. 2022

Acta Chimica Sinica

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Synthesis of arylboronates via the Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates with bis(pinacolato)diboron

Cited by 3 publications

References 79 publications

Recent Expedition in Pd‐ and Rh‐Catalyzed C_(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Recent Expedition in Pd‐ and Rh‐Catalyzed C_(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Efficient system for facile access to ortho-substituted aryl boronates through palladium-catalysed borylation

Recent Advances in the Synthesis of Arylstannanes

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Synthesis of arylboronates via the Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates with bis(pinacolato)diboron

Cited by 3 publications

References 79 publications

Recent Expedition in Pd‐ and Rh‐Catalyzed C(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Recent Expedition in Pd‐ and Rh‐Catalyzed C(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Efficient system for facile access to ortho-substituted aryl boronates through palladium-catalysed borylation

Recent Advances in the Synthesis of Arylstannanes

Contact Info

Product

Resources

About

Recent Expedition in Pd‐ and Rh‐Catalyzed C_(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses

Recent Expedition in Pd‐ and Rh‐Catalyzed C_(Ar)−B Bond Formations and Their Applications in Modern Organic Syntheses