Synthesis of bimetallic Ni-Pt/SAPO-11 composite and the catalytic application in n-heptane hydroisomerization

Abstract

The monometallic Pt/SAPO-11 and bimetallic Ni-Pt/SAPO-11 catalysts were synthesized with Instant Exactness Synthesis (IES) method and characterized by XRD, nitrogen adsorption-desorption, SEM, TEM, FT-IR, Py-IR, NH3-TPD and XPS, and their properties were evaluated for the n-heptane hydroisomerization. The catalysts had spherical structure and moderate acid strength, and exhibited good n-heptane conversion and catalytic selectivity toward n-heptane isomers. Typically, Ni-Pt/SAPO-11 exhibited an isomer selectivity of 80.9% with a conversion of 69.9% at 310 oC, which was obviously better than Pt/SAPO-11 (isomer selectivity of 75.1% with a conversion of 60.6% at 310 oC). Moreover, the Ni-Pt/SAPO-11 catalyst displayed higher percentage of i-heptane (79%) and lower percentage of n-heptane (6%) than Pt/SAPO-11. The continuous test of 360 min indicated Ni-Pt/SAPO-11 catalyst had good catalytic stability. Bimetallic Ni-Pt alloy loaded on SAPO-11 had significantly effect on catalytic properties of n-heptane hydroisomerization.