Synthesis of Chromans from the Reaction of o‐Quinone Methide Precursor with Substituted Styrenes.

Bilgiç, Sevim; Bilgiç, Orhan; Bueyuekkidan, Buelent; Guenduez, Murat

doi:10.1002/chin.200736119

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Chalcogen-phosphorus Compounds1

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“…Nixon also reported 48 the reaction of cyclic P 3 C 2 t Bu 2 CH(SiMe 3 ) 2 with elemental Se which yields the C/P/Se cage compounds below.…”

Section: Chalcogen-phosphorus Compoundsmentioning

confidence: 96%

Oxygen, sulfur, selenium, tellurium and polonium

Clarke

Haynes

Rawson

2008

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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This Chapter reviews the literature concerning the Group 16 elements reported during 2007 with an emphasis on new clusters, heterocycles, reactivity trends and physical properties. HighlightsThe structure of O 8 has been determined crystallographically. New chalcogennitrogen radicals have been shown to exhibit ferromagnetism, conductivity and liquid crystalline properties. New precursors to technologically important transition metal chalcogenides have been reported and structural features for the control of molecular solids have been identified.

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“…Nixon also reported 48 the reaction of cyclic P 3 C 2 t Bu 2 CH(SiMe 3 ) 2 with elemental Se which yields the C/P/Se cage compounds below.…”

Section: Chalcogen-phosphorus Compoundsmentioning

confidence: 96%

Oxygen, sulfur, selenium, tellurium and polonium

Clarke

Haynes

Rawson

2008

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

View full text Add to dashboard Cite

show abstract

“…Recently, Bilgic and Mohinder found that o-quinone methide precursor reacted with 1,3-thiazine or substituted styrenes via the Diels-Alder reaction to give chroman derivatives 2a and 2b, 5 On the other hand, 1,2-naphthoquinone-1-methide dimerized to form a spirodimer 3. 6 We also found that o-quinone methide 4 could be prepared from o-dimethylaminomethylphenol or o-methoxymethylphenol (Scheme 1).…”

Section: Figurementioning

confidence: 99%