“…Among them, ionic salts and coordination compounds (including metal-organic frameworks) are the hotspot materials in the investigations of EMs and they behave significant and special physicochemical performance than other neutral compounds in most cases. [1,2] Azole-based energetic ionic materials are always a fascinating calls of multi-nitrogen frameworks, which contain multiple N-N, C-N chemical bonds and stable electrovalent bond depositing sufficient energy. Since 2010, many energetic ionic compounds grounding on pyrazole were massively prepared, which were mainly consist of 3,4,5-trinitropyrazole (3,4,5-TNP)-, [3,4] 3,4,5-trinitropyrazole-1-ol (TNPO)-, [5] 4-amino-3,5-dinitropyrazole (ADNP)-, 4-nitramino-3, 5-dinitropyrazole (4-NADNP)-and 1-nitramino-3,5-dinitropyrazole (1-NADNP)-based organic salts.…”