Synthesis of cyclopentadienyl iron complexes with substituted phenylene ligands via Suzuki coupling

Ligand Exchange Reaction between Ferrocene and Multiwalled Carbon Nanotubes: A Contemporary Approach

“…In the current work, modification of MWCNT was performed via LER (Scheme ) using ferrocene and a catalytic mixture of AlCl 3 /Al in a molar ratio of 4:1, similar to refs , , and . In addition, a control sample (Fc/MWCNT) without using the catalytic mixture was prepared.…”

“…11 −13 In 1963, 11 years after describing the aromaticity of ferrocene, modification of ferrocene via ligand exchange reaction (LER) was reported. 14 Later, LER was also described for other aromatic and polyaromatic compounds including substituted benzenes, 15 9,10-dimethylanthracene, 16 phenanthrene and its derivatives, 17 picene, 18 sumanene, 19 etc. 20 Taking into account that aromatic clusters vibrationally and electronically might be considered as components of graphite superlattice, 21 in 1999, LER between ferrocene and carbon black and highly oriented pyrolytic graphite (HOPG) in the presence of the AlCl 3 /Al catalytic system was reported for the first time.…”

Generation of Cyclopentadiene for Diels–Alder Reactions by Visible‐Light Irradiation of Iron Sandwich Complexes

“…[12][13][14][15] This ability has been used in organic synthesis for modification and further libera-tion of the arene ligands. In particular, polycyclic arenes, [16,17] cyclophanes, [18] dendrimers, [19] and polymers [20] have been synthesized this way. On the other hand, the same photochemical reaction has been used in organometallic chemistry for the synthesis of (C 5 R 5 )Fe(L) x complexes with various Supporting information for this article is available on the WWW under https://doi.org/10.1002/hlca.202100246 ligands.…”