Synthesis of Disulfides Containing a Corrinoid Head Group for Preparation of Self-Assembled Monolayers

Mendonça, Joana; Luginbühl, Reto; Siegenthaler, H.; Keese, Reinhart

doi:10.1055/s-2005-871941

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Self-assembled Monolayers Of Cobamide-c10-disulfide 5 On Au1

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2007

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“…The structure of the surface coating should provide detailed information about the microenvironment of the catalyst. In persuit of this concept the disulfides 5 and 6, bearing two and one cobamide head group respectively were prepared [19]. The surface of the coated gold electrodes, obtained in the conventional way, was first analyzed by time-of-flight-secondary ion mass spectroscopy (TOF-SIMS) and ESCA.…”

Section: Self-assembled Monolayers Of Cobamide-c10-disulfide 5 On Aumentioning

confidence: 99%

The Quest for Electrodes Coated with Vitamin B12 Derivatives

et al. 2007

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The electrochemical control of the redox reactions of vitamin B12 and derivatives thereof plays an important role for the in vivo investigations of the B12 dependent biological transformations. While most of these studies were performed in solution, electrodes coated with appropriate B12 derivatives are of more recent interest. A survey of our results in preparing electrodes bearing B12 derivatives is given. Structural features of the surface coating are discussed. Some of the electrodes show catalytic activity for the reduction of oxygen.

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Section: Self-assembled Monolayers Of Cobamide-c10-disulfide 5 On Aumentioning

confidence: 99%