2024
DOI: 10.1039/d4ob00011k
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Synthesis of enantioenriched spirocyclic 2-arylpiperidines via kinetic resolution

Anthony Choi,
Anjan Das,
Anthony J. H. M. Meijer
et al.

Abstract: Kinetic resolution of N-Boc-spirocyclic 2-arylpiperidines with spiro substitution at C-4 was achieved with high enantiomeric ratios using the chiral base n-BuLi/sparteine. Cyclopropanation or metallaphotoredox catalysis were used to access the...

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