2022
DOI: 10.1002/ejoc.202101502
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Synthesis of Fatty Acid Bioconjugates and Related Derivatives

Abstract: Several families of naturally occurring fatty acid conjugates are presented. Chemical and chemoenzymatic syntheses are exemplified for fatty acid conjugates with (poly)phenols, glycerol, hydroxyfatty acids, aminoacids and small peptides.

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Cited by 5 publications
(4 citation statements)
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References 95 publications
(158 reference statements)
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“…alternative of bioconjugation of p-MCA with a single chain of a fatty acid, as reported for other bioactive molecules [8], favors aggregation of the new UV filter through additional van der Waals non-covalent interactions between hydrophobic aliphatic chains, which might enhance the photodegradation of the bioconjugate and, as a consequence, was not taken into consideration. Moreover, the significant molecular mass of the designed bioconjugates and their increased hydrophobicity will prevent percutaneous absorption of the UV absorber and the subsequent effects on humans.…”
Section: Resultsmentioning
confidence: 99%
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“…alternative of bioconjugation of p-MCA with a single chain of a fatty acid, as reported for other bioactive molecules [8], favors aggregation of the new UV filter through additional van der Waals non-covalent interactions between hydrophobic aliphatic chains, which might enhance the photodegradation of the bioconjugate and, as a consequence, was not taken into consideration. Moreover, the significant molecular mass of the designed bioconjugates and their increased hydrophobicity will prevent percutaneous absorption of the UV absorber and the subsequent effects on humans.…”
Section: Resultsmentioning
confidence: 99%
“…Bioconjugation of lipids with biologically active molecules, for example, phenolic antioxidants, yields potentially new therapeutic molecules with increased bioaccessibility and positive pharmacological evaluation on oxidative stress, skin regeneration, and antiinflammatory properties [8].…”
Section: Introductionmentioning
confidence: 99%
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“…Recent studies addressed the stability improvement in body fluids [ 8 ], the cell penetration enhancement [ 9 ], and the capacity for synergetic improvement of biological properties of FAs conjugated with phenolic compounds [ 10 , 11 ].…”
Section: Introductionmentioning
confidence: 99%