Synthesis of ferrocene-labelled 2-aminopyrimidine derivatives via homogeneous catalytic carbonylation

Fehér, Csaba; Habuš, Ivan; Skoda‐Földes, Rita

doi:10.1007/s00706-014-1299-1

Cited by 1 publication

(1 citation statement)

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“…As a continuation of our work concerning ferrocene-labeled pyrimidine derivatives, in the present study we report on a three-step synthesis of new 2-ureido-4-ferrocenyl pyrimidines and investigation of their host–guest interactions with 2,6-diaminopyridine.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of 2-Ureido-4-ferrocenyl Pyrimidine Guests. Investigation of Complementary Molecular Recognition of 2,6-Diaminopyridine

Fehér

Papp

Gömöry³

et al. 2016

Organometallics

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%Johan%Wouters, d %György%Lendvay, e,f %Rita% SkodaGFöldes* a % a %Institute%of%Chemistry,%Department%of%Organic%Chemistry,%University%of%Pannonia,%Egyetem%u.%10.%(P.O.Box%158)%HG 8200%Veszprém,%Hungary% b %Instrumentation%Center,%Research%Centre%for%Natural%Sciences,%Hungarian%Academy%of%Sciences,%HG1117%Budapest,% Hungary%%% c %János%Szentágothai%Research%Center,%University%of%Pécs,%Ifjúság%útja%20,%HG7624%Pécs,%Hungary% d %Department%of%Chemistry,%University%of%Namur,%BG5000%Namur,%Belgium% e %Institute%of%Chemistry,%Department%of%General%and%Inorganic%Chemistry,%University%of%Pannonia,%%HG8200% Veszprém,%Hungary% f %Institute%of%Materials%and%Environmental%Chemistry,%Research%Centre%for%Natural%Sciences,%Hungarian%Academy%of% Sciences,%HG1117%Budapest,%Hungary%% % Supporting*Information*! ABSTRACT:%Novel%2GureidoG4Gferrocenylpyrimidines%have%been%synthesized%from%iodoferrocene%by%a%threeGstep%reaction% sequence.%XRD%analysis%and%spectroscopic%data%support%the%presence%of%an%intramolecular%hydrogen%bond%between%a%niG trogen%atom%of%the%pyrimidine%ring%and%an%NH%group%of%the%urea%moiety.%Both%theoretical%calculations%and%NMR%investiG gations%prove%the%existence%of%two%isomeric%forms%in%solution%both%of%which%can%form%hydrogen%bonds%with%an%appropriate% guest%via%an%acceptor%-%donor%-%acceptor%bonding%pattern.%Complexation%with%2,6Gdiaminopyridine%can%be%proved%either% by%NMR%spectroscopy%or%by%electrochemical%measurements.% % INTRODUCTION)Ferrocene%and%its%derivatives%are%the%most%commonly%used% mediators% in% amperometric% biosensors.

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Section: Introductionmentioning

confidence: 99%