Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

Davidson, Jillian J.; Gunther, S. Olivia; Leong, Derek W.; Ozerov, Oleg V.

doi:10.1039/d3dt02127k

Dalton Trans.

2023

DOI: 10.1039/d3dt02127k

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Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

Jillian J. Davidson,

S. Olivia Gunther,

Derek W. Leong

et al.

Abstract: Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF3, and Br substituents showing quasi-reversible redox events in the 0.59 – 1.32 V range is reported. Chemical oxidation of the...

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2024

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Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants

Saju,

Crawley,

MacMillan

et al. 2024

J. Am. Chem. Soc.

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We report herein a convenient one-pot synthesis for the shelf-stable molecular complex [Mn(NO 3 ) 3 (OPPh 3 ) 2 ] (2) and describe the properties that make it a powerful and selective one-electron oxidation (deelectronation) reagent. 2 has a high reduction potential of 1.02 V versus ferrocene (MeCN) (1.65 vs normal hydrogen electrode), which is one the highest known among readily available redox agents used in chemical synthesis. 2 exhibits stability toward air in the solid state, can be handled with relative ease, and is soluble in most common laboratory solvents such as MeCN, dichloromethane, and fluorobenzene. 2 is substitutionally labile with respect to the coordinated (pseudo)halide ions enabling the synthesis of other new Mn(III) nitrato complexes also with high reduction potentials ranging from 0.6 to 1.0 V versus ferrocene.

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Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants

Saju,

Crawley,

MacMillan

et al. 2024

J. Am. Chem. Soc.

View full text Add to dashboard Cite

show abstract

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Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

Abstract: Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF3, and Br substituents showing quasi-reversible redox events in the 0.59 – 1.32 V range is reported. Chemical oxidation of the...

Cited by 1 publication

References 50 publications

Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants

Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants

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