Synthesis of Fluoroalkyl Vinyl Sulfoxides and their Use in Diels-Alder Reactions

Moïse, Joëlle; Goumont, Régis; Magnier, Emmanuel; Wakselman, Claude

doi:10.1055/s-2004-831201

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Cited by 3 publications

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Formation of Alkenes by Diels–Alder Reactions

Larock

2018

Comprehensive Organic Transformations

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General Reviews Regioselectivity Exo / Endo Selectivity Asymmetric Diels–Alder Reaction Mechanism Use of High Pressure Microwave Irradiation Infrared Irradiation Mechanical Ball Milling Ultracentrifugation Use of Ultrasound Catalysis Solvent Effects Cavity Effects Retro‐Diels–Alder Reaction Intramolecular Diels–Alder Reaction Inverse Electron‐Demand Diels–Alder Reaction Radical Cation Diels–Alder Reaction Ionic Diels–Alder Reaction Use of Heterodienophiles Use of Heteroatom‐Containing “Dienes” Use of Substituted 1,3‐Dienes o ‐Quinodimethanes and Heterocyclic Analogues Arynes and Hetarynes Some Other Dienophiles Dienophile Equivalents Transition Metal Carbenes as Dienophiles

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Formation of Alkenes by Diels–Alder Reactions

Larock

2018

Comprehensive Organic Transformations

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Chalcogen-containing analogs of ethylene glycol and its derivatives

et al. 2008

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Synthetic Strategies Towards and Around the CF3S(O) Structural Motif

Romanenko

2023

COC

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This account reviews synthetic strategies for constructing and transforming CF3S(O) structural moiety developed during the last decades. Existing paths to the synthesis of CF3S(O)-containing organic molecules are demonstrated. Among these are direct trifluoromethanesulfinylation reactions, oxidation of compounds having CF3S function, substitutive trifluoromethylation reactions of sulfinic acid halides and esters, and rearrangement reactions. The reactivity and substituent modification procedures are covered. Also included are sections on the synthetic application of the CF3S(O)-bearing molecules for the design of biologically important molecules and synthesis of other organofluorine compounds.

show abstract

Synthesis of Fluoroalkyl Vinyl Sulfoxides and their Use in Diels-Alder Reactions

Cited by 3 publications

References 20 publications

Formation of Alkenes by Diels–Alder Reactions

Formation of Alkenes by Diels–Alder Reactions

Chalcogen-containing analogs of ethylene glycol and its derivatives

Synthetic Strategies Towards and Around the CF3S(O) Structural Motif

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