Synthesis of four pyrene-containing chalcone derivatives: Achieving excellent third-order nonlinear optical properties by optimizing halopyridines

Sun, Jinyu; Wang, Guilin; Liu, Chengqi; Yufang, Shi; Ming-gen, Zhao

doi:10.1016/j.optlastec.2018.08.038

Cited by 31 publications

(9 citation statements)

References 46 publications

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“…Among various method of Z-scan techniques, the 4f coherent imaging system as a new measurement to determine third-order NLO properties has many advantages such as single laser shot, no sample movement, lower sensitivity to statistical fluctuations of the laser beam and higher sensitivity to characterize the uneven surface of thin films. 41 Due to its advantages mentioned above, 4f coherent imaging system is suitable to measure the third-order NLO properties of nanofilms.…”

Section: F Coherent Imaging Techniquementioning

confidence: 99%

Highly broadband NLO response of acceptor–donor–acceptor materials with a planar conformation

Huang

Zhou

et al. 2021

Mater. Adv.

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Section: F Coherent Imaging Techniquementioning

confidence: 99%

Highly broadband NLO response of acceptor–donor–acceptor materials with a planar conformation

Huang

Zhou

et al. 2021

Mater. Adv.

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“…Organic nonlinear optical (NLO) materials with high nonlinearities have been widely used in biological probes, laser dyes, various therapies, and sensing. − The high nonlinearities are the result of optimum combinations of various characteristics, such as the molecular conformation, conjugation length, and transport properties; , hence, further explorations of NLO enhancement principles are of great interest. A π-conjugated system and an electron donor–acceptor structure are important mechanisms for generating organic materials with optical nonlinearity, and pyrenyl and pyrene-based derivatives are representative examples of π-conjugated systems. − …”

Section: Introductionmentioning

confidence: 99%

D–π–A-Type Pyrene Derivatives with Different Push–Pull Properties: Broadband Absorption Response and Transient Dynamic Analysis

Niu

Wang

et al. 2020

J. Phys. Chem. C

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The nonlinear absorption properties and excited-state dynamics of two linear D−π–A pyrene derivatives (B1 and B2) with different push–pull properties were investigated and compared. The transient absorption spectra provide information about their excited states, revealing a transition from the local excited (LE) state to the charge transfer (CT) state in each of the compounds. The Z-scan measurements show that both derivatives exhibit reverse saturable absorption at multiple excitation widths (fs, ps, and ns). Combined with quantum chemical calculations, the experimental results indicate that B1 (with pyrene as the donor) shows superior two-photon absorption (TPA) at shorter wavelengths (≤650 nm) because of more π–π* transition and that the stronger CT to the pyrene group contributes to the resonance enhancement of the TPA of B2 (with pyrene as the acceptor) at near-infrared wavelengths. In addition, both compounds exhibit satisfactory optical limiting performance, while the thresholds of B2 are 0.0029–0.01 and 0.092 J/cm2 under excitation by femtosecond (532–900 nm) and picosecond (532 nm) pulses, respectively.

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“…Charge transfer takes place through the delocalized electron along a π-conjugation bridge, which contributes to the large electron density in the molecule. Hence, nonlinear optical effect may get enhanced [65,66]. According to Liu et al [25], if the molecules have elongated π-conjugation then the maximum absorbance peak is shifted to shorter wavelength.…”

Section: Structure-property Relationmentioning

confidence: 99%

A third-order nonlinear optical single crystal of 3,4-dimethoxy-substituted chalcone derivative with high laser damage threshold value: a potential material for optical power limiting

Parol

Prabhu

Taher

et al. 2020

J Mater Sci: Mater Electron

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Third-order nonlinear optical material 4-[(1E)-3-(3,4-dimethoxyphenyl)-3-oxoprop-1-en-1-yl]phenyl 4-methylbenzene-1-sulfonate (DMPMS) is crystallized by slow solvent evaporation technique. The crystal has inversion symmetry and belongs to monoclinic system with $${P2}_{1}/c$$ P 2 1 / c space group. The C–H⋯O/C–H⋯π intermolecular interactions will be large complementarity for molecular density/crystal packing. A comprehensive investigation for absorbance and emission properties has been performed. Thermal stability is up to 258 °C without any weight loss and calculated value of laser damage threshold is ≈ 12 GW/cm2. The DMPMS shows low dielectric constant value, about 4.42 at 1 MHz and electronic polarizability values in the order of $${10}^{-23}$$ 10 - 23 cm3. Furthermore, theoretical calculation has been performed using B3LYP and M06-2X functional. The static first-order hyperpolarizability parameter is 55 (B3LYP) and 34 (M06-2X) times that of urea. The total contribution of second-order hyperpolarizability is − 37.9 $$\times {10}^{-40 }\mathrm{esu}$$ × 10 - 40 esu (in B3LYP functional) and − 25.77 $$\times {10}^{-40 }\mathrm{esu}$$ × 10 - 40 esu (in M06-2X functional), respectively. Here, two-photon absorption mechanism is responsible for nonlinear absorption and co-efficient is found to be $$28.3 \times {10}^{-12}$$ 28.3 × 10 - 12 m/W. In optical limiting study, limiting threshold is found to be 65 µJ. The real and imaginary third-order nonlinear optical susceptibility is of the order $${10}^{-12} \mathrm{esu}$$ 10 - 12 esu .

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Synthesis of four pyrene-containing chalcone derivatives: Achieving excellent third-order nonlinear optical properties by optimizing halopyridines

Cited by 31 publications

References 46 publications

Highly broadband NLO response of acceptor–donor–acceptor materials with a planar conformation

Highly broadband NLO response of acceptor–donor–acceptor materials with a planar conformation

D–π–A-Type Pyrene Derivatives with Different Push–Pull Properties: Broadband Absorption Response and Transient Dynamic Analysis

A third-order nonlinear optical single crystal of 3,4-dimethoxy-substituted chalcone derivative with high laser damage threshold value: a potential material for optical power limiting

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