Synthesis of functional polyacrylamide (co)polymers by organocatalyzed post-polymerization modification of non-activated esters

Li, Guoqing; Zhang, Zhiyi; Xiao, Wenhao; Wu, Tongtong; Xu, Jinbao

doi:10.1039/d3ra04667b

RSC Adv.

2023

DOI: 10.1039/d3ra04667b

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Synthesis of functional polyacrylamide (co)polymers by organocatalyzed post-polymerization modification of non-activated esters

Guoqing Li,

Zhiyi Zhang,

Wenhao Xiao

et al.

Abstract: Synthesis of functional polyacrylamide (co)polymers by organocatlyted post-polymerization modification of poly(2,2,2-trifluoroethyl acrylate).

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2024

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Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Weingarten,

Adams

2024

ACS Macro Lett.

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A controlled polymerization using activated acrylate monomers via ARGET-ATRP is developed with a tris[(4-dimethylamino pyridyl)methyl]amine ligand to address issues with weaker ligands and monomers that can undergo postpolymerization functionalization. This catalyst system enables the polymerization of N-acryloxy succinimide, fluorinated monomers, and isocyanato ethyl acrylate under controlled homogeneous conditions, ensuring linear molecularweight growth and low polydispersity. Two block copolymerization strategies produce amphiphilic copolymers with narrow molecular-weight distributions and customizable compositions, allowing for various postpolymerization functionalizations.

show abstract

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Weingarten,

Adams

2024

ACS Macro Lett.

View full text Add to dashboard Cite

show abstract

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Synthesis of functional polyacrylamide (co)polymers by organocatalyzed post-polymerization modification of non-activated esters

Abstract: Synthesis of functional polyacrylamide (co)polymers by organocatlyted post-polymerization modification of poly(2,2,2-trifluoroethyl acrylate).

Cited by 1 publication

References 53 publications

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

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Synthesis of functional polyacrylamide (co)polymers by organocatalyzed post-polymerization modification of non-activated esters

Abstract: Synthesis of functional polyacrylamide (co)polymers by organocatlyted post-polymerization modification of poly(2,2,2-trifluoroethyl acrylate).

Cited by 1 publication

References 53 publications

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMANMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMANMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Contact Info

Product

Resources

About

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization