Synthesis of functionalized S-benzyl dithiocarbamates from diazo-compounds via multi-component reactions with carbon disulfide and secondary amines

Abstract

Triflic acid promoted multi-component synthesis of functionalized S-benzyl dithiocarbamates from diazo compounds, carbon disulfide and secondary amines is reported. The reactions proceeded at room temperature and gave the desired dithiocarbamates...

Variable non-covalent interactions in the crystals of a series of 4-Y-benzyl pyrrolidine-1-carbodithioates: Y = Cl, Br, I, Me and NO2

“…activities. 31,32 Prominent among these are S-benzyl esters 33 as are pyrrolidine dithiocarbamates. [34][35][36] As an extension of work exploring the potential biological activity of metal dithiocarbamates, including pyrrolidine derivatives, [37][38][39] and systematic studies of molecules that differ only in the nature of a small substituent, [40][41][42][43] a series of five S-benzyl esters of pyrrolidine dithiocarbamate were investigated which differ in the nature of the substituent in the 4-position of the terminal phenyl group.…”

Open-[60]fullerene–aniline conjugates with near-infrared absorption

“…It is well-known that the reaction of primary amine with CS 2 affords corresponding dithiocarbamic acid. 12 In our reaction system, however, the addition of the dithiocarbamic acid to 2 unlikely occurs since it requires a Cu( ii )/O 2 catalyst for the more simple case of pristine [60]fullerene. 12 a Therefore, 3 is considered to be formed via an alternative scheme (Fig.…”