Synthesis of Gold‐Containing Mixed‐Metal Cluster Complexes

Synthesis and in vitro evaluation of gold(I) thiosemicarbazone complexes for antimalarial activity

“…In terms of coordination chemistry, this class of compounds are versatile N,S donors ligands and their coordination to metal ions is well documented [16,17]. Due to a limited number of gold(I) TSC compounds reported in the literature [16,18,19] and the common use of gold(I) complexes [Au I (Ph 3 P)Cl] [20], [Au I (THT)Cl] [21,22] and [Au I (SMe)Cl] [23,24] as starting materials, Lobana and co-workers investigated the reaction involving AuCl 3 with TSCs [25]. This led to the isolation of a gold(I) complex with two TSC ligands linearly coordinated to gold(I) centre.…”

Solvent Dependence of the Single Molecule Conductance of Oligoyne-Based Molecular Wires

“…NEt 3 was purified by distillation from CaSO 4 , other reaction solvents were purified and dried using Innovative Technology SPS-400 and, if necessary, degassed before use. The compounds AuCl(PPh 3 ), 21 Me 3 Si-(CC) 3 Mass spectra were measured on a Waters Xevo OtoFMs with an Atmospheric Solids Analysis Probe (ASAP). Electron ionization mass spectra were recorded on a Thermoquest…”

Group 11 complexes with the 1,1′Bis[N,N′-(2-(diphenylphosphino) amide] ferrocene ligand

“…The gold(I) atom is bonded to the amido nitrogen of one of the phosphine chains and to the phosphorous atom of the other. The geometry around the gold atom is almost linear as shown by the angle P-Au-N 176.61° (19). The deviation from linearity may be due to the strong interaction between the two gold atoms (Au-Au distance = 2.8921(5) Å).…”