Multilayer graphene (MLGR) and its bulk analog, highly oriented pyrolytic graphite (HOPG), were treated by radio frequency activated low pressure N 2 gas plasma (at negative bias 0 - pyrrole-and triazine-type at 399.7 eV and N substituting C in graphite-like network at 400.9 eV) were determined from high-resolution N1s spectral region for all samples. Pyridine and pyrrole-triazine components increase preferentially with increasing bias. Alterations of the C1s and O1s spectra are discussed in a critical approach. The amount of reacted carbon was consistent with that required for the three different nitrogen and oxygen states, thus validating the proposed assignments.