2024
DOI: 10.1021/acs.orglett.4c02769
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Synthesis of Heptacyclic Compounds through C–H Bond Activation-Initiated Cascade Reactions

Xing He,
Kangli Liu,
Shengnan Yan
et al.

Abstract: Presented herein is an atom-and step-economical method enabling the precise assembly of a heptacyclic scaffold containing both azocine and indoline units through the cascade reactions of indolin-1-yl(aryl)methanimines with diazo indanediones. The formation of products involves C−H bond activation and double carbene insertion followed by intramolecular condensation, retro-[2 + 2] cycloaddition, and recyclization. This cascade reaction not only provided a concise and straightforward strategy for the synthesis of… Show more

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Cited by 4 publications
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