2004
DOI: 10.1007/s11176-005-0137-x
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Synthesis of heterobimetallic zinc complexes and their catalytic properties in reactions of CO2 with cyclohexene oxide

Abstract: The reaction of Et 2 Zn with NaOCH 2 CH 2 OH yielded a bimetallic zinc complex NaOCH 2 CH 2 .

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Cited by 8 publications
(2 citation statements)
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References 12 publications
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“…The copolymerization of CO 2 and cyclohexene oxide, catalyzed by [Cp 2 Ti­(OCH 2 CH 2 OZnEt) 2 ] under ambiant conditions, afforded the corresponding poly­(cyclohexene carbonate) (Scheme ). After 100 h of reaction, 3.6 g of polymer per g of catalyst were obtained …”
Section: Reactions In the Presence Of Heterometallic Catalystsmentioning
confidence: 99%
“…The copolymerization of CO 2 and cyclohexene oxide, catalyzed by [Cp 2 Ti­(OCH 2 CH 2 OZnEt) 2 ] under ambiant conditions, afforded the corresponding poly­(cyclohexene carbonate) (Scheme ). After 100 h of reaction, 3.6 g of polymer per g of catalyst were obtained …”
Section: Reactions In the Presence Of Heterometallic Catalystsmentioning
confidence: 99%
“…The design and development of molecular precursor reagents for chemical vapour deposition (CVD) is a well-established route to create thin films with potential advantages such as high crystallinity, spatially oriented nanostructure, excellent control over homogeneity, stoichiometry and reproducibility of the final product at relatively lower temperatures. 18 Cp 2 Ti(OCH 2 CH 2 OZnEt) 2 19 and Zn 2 Ti 4 (μ 3 -O) 2 (μ 2 -O) 2 (OiPr) 2 (μ 2 -OMc) 10 20 are known and none of these compounds has been employed as CVD precursors for the deposition Zn-Ti ceramic oxides. Our step by step synthesis has resulted in numerous well defined titanium-based heterobimetallic complexes such as [Mn 2 Ti 4 (TFA) 8 (THF) 6 (OH) 4 (O) 2 ]⋅0.4THF, [Ti 4 (dmae) 6 (μ-OH)(μ-O) 6 Cu 6 (2-methylbenzoate) 9 ] 25 ,…”
Section: Introductionmentioning
confidence: 99%