2015
DOI: 10.1134/s1070428015100140
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Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions

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“…The reaction of 1,3,7-triazapyrene ( 3 ) with electron-rich arenes in concentrated hydrochloric acid yields a limited amount of 6-aryl-1,3,7-triazapyrenes (Scheme , route B) . Oxidative nucleophilic alkoxylation (Scheme , route C) and (alkyl)­amination (Scheme , routes D (S N H ) and E have also been examined to deliver C(6)-heterosubstituted 1,3,7-triazapyrenes. Interestingly, only the C(6)-regioisomer has been obtained for those examples.…”
Section: Introductionsupporting
confidence: 85%
“…The reaction of 1,3,7-triazapyrene ( 3 ) with electron-rich arenes in concentrated hydrochloric acid yields a limited amount of 6-aryl-1,3,7-triazapyrenes (Scheme , route B) . Oxidative nucleophilic alkoxylation (Scheme , route C) and (alkyl)­amination (Scheme , routes D (S N H ) and E have also been examined to deliver C(6)-heterosubstituted 1,3,7-triazapyrenes. Interestingly, only the C(6)-regioisomer has been obtained for those examples.…”
Section: Introductionsupporting
confidence: 85%