2016
DOI: 10.1016/j.jcis.2015.09.062
|View full text |Cite
|
Sign up to set email alerts
|

Synthesis of higher alcohols over highly dispersed Cu–Fe based catalysts derived from layered double hydroxides

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2
1

Citation Types

2
24
0

Year Published

2017
2017
2024
2024

Publication Types

Select...
7

Relationship

0
7

Authors

Journals

citations
Cited by 43 publications
(26 citation statements)
references
References 42 publications
2
24
0
Order By: Relevance
“…This may render an optimized rate of C–C bond propagation on iron carbide sites and CO insertion on Cu/Fe 5 C 2 interfacial sites, and thus a high selective toward long-chain alcohols would be achieved. Layered double hydroxides (LDHs), with unique structure that metal cations are distributed in the hydroxide layers at an atomic level, have attracted extensive attention as catalyst precursors for higher alcohols synthesis 10,15,18,28,29 .…”
Section: Introductionmentioning
confidence: 99%
“…This may render an optimized rate of C–C bond propagation on iron carbide sites and CO insertion on Cu/Fe 5 C 2 interfacial sites, and thus a high selective toward long-chain alcohols would be achieved. Layered double hydroxides (LDHs), with unique structure that metal cations are distributed in the hydroxide layers at an atomic level, have attracted extensive attention as catalyst precursors for higher alcohols synthesis 10,15,18,28,29 .…”
Section: Introductionmentioning
confidence: 99%
“…The mixed oxides typically possessed the large specific surface areas, thermal stability, and synergic interactions between the different metal components. Therefore, LDHs calcination products have found numerous applications in various catalytic processes [1012]. …”
Section: Introductionmentioning
confidence: 99%
“…When acting as an active component, Fe co-exists with Cu nanoparticles in close proximity, favors the formation of alcohol over hydrocarbons. [10a] The interpretation was further supported by others, [11][12][13] where higher alcohol synthesis was favored due to the synergetic effect of the active and stable CuÀ Fe dual sites. The physicochemical properties of the catalysts were significantly influenced by the Cu/Fe molar ratio, which determined the interaction of Cu and Fe, [12][13] thereby affecting the selectivity towards higher alcohols.…”
Section: Effect Of Promotermentioning
confidence: 75%
“…Han and his team [12] investigated the role of layered double hydroxide‐derived copper and iron‐based catalysts for CO hydrogenation to higher alcohols. The study showed that increasing the copper‐to‐iron molar ratio from 0.2 to 1.0 increased the copper reduction temperature and the layer spacing until the ratio reached 0.5, above which both parameters decreased.…”
Section: Co Hydrogenation To Higher Alcoholsmentioning
confidence: 99%
See 1 more Smart Citation