The
adsorption mechanism of Cr
6+
on biochar prepared
from corn stalks (raw carbon) was studied by extracting the organic
components (OC) and inorganic components (IC). Scanning electron microscopy,
X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray
photoelectron spectroscopy were used to characterize the properties
of three kinds of carbon. Kinetic and thermodynamic experiments were
performed. The results showed that the experimental data were fitted
well by the Freundlich model and the pseudo-second-order kinetic model,
and the adsorptions on the three kinds of carbon were all spontaneous,
endothermic processes. The adsorption of Cr
6+
by biochar
was in accordance with a chemisorption process. The adsorption contribution
rate of the OC was 97%, which was much higher than that of the IC.
Electrostatic attraction and redox reaction were the main mechanisms
of adsorption, and among them, the contribution rate of the redox
reaction accounted for 61.49%. The reduced Cr
3+
could both
exchange ions with K
+
and dissociate into solution by electrostatic
repulsion; the amount of Cr
3+
released into the solution
was approximately 17.07 mg/g, and the amount of Cr
3+
ions
exchanged with K
+
was 0.29 mg/g. These results further
elucidate the adsorption mechanism of Cr
6+
by biochar.