Synthesis of magnetically recyclable ZIF-8@SiO2@Fe3O4 catalysts and their catalytic performance for Knoevenagel reaction

Preparation of magnetic metal-organic frameworks with high binding capacity for removal of two fungicides from aqueous environments

“…Good agreement between experimental and calculated results verified that the Langmuir adsorption isotherm model was suitable for the adsorption of TCS and TCC on the MMOFs. The saturated adsorption capacities of TCS on MMOFs were extremely higher than that on non-magnetic UiO-66 reported (98 mg g À1 ) [58]. High magnetic saturation strength along with the excellent binding capacity made the MMOFs as a supreme versatile adsorbent for influential uptake of pollutants in order to purify the environment water.…”

“…Within 10 min, the adsorption amount increased rapidly with adsorption time increasing owing to vacant binding sites, and then gradually reached equilibrium by saturation of adsorbent. The equilibrium time of the adsorption experiment was 25 min, which is much lower than that of other MOFs [58,66].…”

“…The synthesis process and conditions of proposed MMOFs were compared with the reported synthetic methods of common MMOFs [48,[56][57][58]. As can be seen from Table S1, the preparation of common MMOFs needs more complicated experimental equipment, more amounts of (toxic) reagents and higher temperature control.…”

The fabrication of magnetic metal-organic frameworks composites and their application in environment

“…Fe3O4@SiO2@HKUST-1 吸附Hg 2+ [39] Fe3O4@SiO2@ZIF-8 催 化 [46] Fe3O4@SiO2@UiO-66 萃取软骨藻酸 [42] Fe3O4@C@ZIF- 2014年, Jiang等 [48] 采用相同的策略, 将PVP处理的 Fe3O4纳米颗粒成功镶嵌在ZIF-8中. 在吸附水中羟基 醌的实验中, 表现出超高的吸附性能和良好的磁分离 性质.…”

Chemical fixation of carbon dioxide catalyzed by magnetically recoverable NH2-MIL-101(Al) as an elegant nanoreactor

“…Since catalyst recovery and reuse are very important features in many catalytic processes, these days magnetization of metal-organic frameworks has received considerable attention to provide much easier and faster separation of the catalyst from the reaction media by using an external magnetic field instead of performing tedious centrifugation and filtration steps [23,[27][28][29][30][31].…”