Nano ceramics of pure TiO 2 and Dy 3+ , Eu 3+ and Tb 3+ doped TiO 2 are prepared by hydrothermal method and these are characterized by using X-ray diffractometer (XRD), UV-Visible spectroscopy, field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), and photoluminescence spectroscopy. XRD analysis revealed that the average particle size of the pure TiO 2 and Dy 3+ , Eu 3+ and Tb 3+ doped TiO 2 are in the range of 45-35 nm and confirms the anatase phase. The FESEM and HRTEM analysis confirm that the obtained ceramics are in nano regime. The absorption spectrum revealed that the bandgap of the TiO 2 ceramics are in the range 3.14-3.2 eV. The PL analysis showed that the doping of Dy 3+ , Eu 3+ and Tb 3+ had improved the luminescence behavior than the pure TiO 2 nanoparticles. Overall, by doping 0.5 mol% concentration of rare earth (RE) greatly alters the structural morphology and directly influence the luminescence behavior of TiO 2 and suitable for advanced optoelectronic applications. The color purity of the studied samples is found to be 91% for Dy 3+ , 84% for Eu 3+ and 73% for Tb 3+ at the excitation of 345 nm, 376 nm and 350 nm respectively. The single-doped sample Eu 3+ : TiO 2 , Tb 3+ : TiO 2 and Dy 3+ : TiO 2 samples showed orange-red, blue-green and white emissions respectively.