Synthesis of metal–organic frameworks (MOFs) and their application in the selective catalytic reduction of NO_x with NH₃

Abstract

Metal-organic framework (MOFs) materials have attracted much attention as catalysts because of their high surface area, controllable pore size and expected chemical functionalities. Hence, energy storage, sensing, gas storage, adsorption...

Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

“…3 shows some methods used to synthesize MOFs. 67 MOFs provide considerably large surface areas, consistent adjustable pore sizes, and signicant pore volumes. At the same time, they can also perform various tasks as their metal nodes and ligands are easily modied, 68 making them suitable candidates as catalysts and electrode materials.…”

Preparation of chiral metal–organic framework l-his-MIL-53-NH2@SiO2 composite by in situ growth and chiral post-modification strategies for HPLC enantiomeric separation

“…Metal–organic frameworks (MOFs) are periodic porous materials formed by self-assembly of metal ions or metal clusters with organic ligands. 1–3 Since MOFs are characterized by rich topology, adjustable pore size, controllable functional groups, and high specific surface area, they have a wide range of applications in catalysis, 4,5 gas storage, 6 separation, 7–9 drug delivery, 10,11 sensing, 12 and so on. As an important branch of MOFs, chiral metal–organic frameworks (CMOFs) with abundant chiral recognition sites and good spatial selectivity have been widely used in membrane separation, 13 chromatographic separation, 14,15 and asymmetric catalysis.…”

Preparation of core–shell catalyst for the tandem reaction of amino compounds with aldehydes

“…[24][25][26][27][28] MOFs are a relatively new class of porous materials that form open crystalline frameworks with permanent porosity by linking metal-containing units with organic linkers, [29][30][31] with tunable pore sizes, well-dened metal nodes, tunable chemical composition, and surface function. [32][33][34][35][36] There are many advantages to supporting the noble metals on the MOFs. For example: the noble metals NPs are highly dispersed on the MOFs to prevent NPs agglomeration and reduce metal load; the sites required for the catalysts can be obtained from the well-dened metal nodes; the tunable pore sizes may facilitate the ability to catalyze reactants with various molecular sizes.…”