Synthesis of Mixed Ladder-Like Polysilsesquioxanes by Copolymerization of 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane and Dodecyltrimethoxysilane

Wolpert, Adam; Lai, Ziruo; Wu, Gang; Liu, Guojun

doi:10.1021/acs.macromol.4c00375

Macromolecules

2024

DOI: 10.1021/acs.macromol.4c00375

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Synthesis of Mixed Ladder-Like Polysilsesquioxanes by Copolymerization of 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane and Dodecyltrimethoxysilane

Adam Wolpert,

Ziruo Lai,

Gang Wu

et al.

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Cited by 3 publications

References 39 publications

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Smudge-resistant antimicrobial ladder-like polysilsesquioxane coatings

Shum,

Liu

2025

Progress in Organic Coatings

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Smudge-resistant antimicrobial ladder-like polysilsesquioxane coatings

Shum,

Liu

2025

Progress in Organic Coatings

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Poly(3,4-epoxycyclohexylmethyl acrylate) Synthesis and Use in the Preparation of an Exceptionally Hard yet Flexible Organic Polymer Coating

Seck,

Lai,

Liu

2024

Macromolecules

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Dynamic silicone hydrogel gauze coatings with dual anti-blood adhesion mechanism for rapid hemostasis and minimal secondary damage

Xu,

Chen,

et al. 2024

Sci. Adv.

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Hemostatic materials that can rapidly control bleeding without causing secondary damage or sharp pain upon removal are receiving increasing demands in acute trauma treatments and first-aid supplies. Here, we report the development of a dynamic silicone hydrogel coating on medical gauze to enable rapid hemostasis and synergistic anti-blood adhesion properties. The silicone hydrogel can spontaneously form oriented cross-linked structures on fibrous medical gauze through a solution-processing method to achieve macroscopic superhydrophobicity with microscopic surface slipperiness, resulting in excellent anti-blood adhesion with the on-wound peeling force at ~0 millinewton. The development of dynamic silicone hydrogel coating on medical gauze enables a unique integration of advanced features including instant bleeding control, excellent anti-blood adhesion, and excellent air permeability. The proposed strategy is also suitable for scalable production, making it promising in the applications of trauma management.

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Synthesis of Mixed Ladder-Like Polysilsesquioxanes by Copolymerization of 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane and Dodecyltrimethoxysilane

Cited by 3 publications

References 39 publications

Smudge-resistant antimicrobial ladder-like polysilsesquioxane coatings

Smudge-resistant antimicrobial ladder-like polysilsesquioxane coatings

Poly(3,4-epoxycyclohexylmethyl acrylate) Synthesis and Use in the Preparation of an Exceptionally Hard yet Flexible Organic Polymer Coating

Dynamic silicone hydrogel gauze coatings with dual anti-blood adhesion mechanism for rapid hemostasis and minimal secondary damage

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