Synthesis of molybdenocene(IV) and tungstenocene(IV) tropolonato complexes: Its derivative containing calix[4]arene moiety

Minato, M.; Ren, Junyu; Kasai, Masahiko; Munakata, Koji; Ito, Takashi

doi:10.1016/j.jorganchem.2005.07.118

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Reactions Of the Di-μ-hydroxo Dinuclear Complexes With Tropo1

Synthesis Of the Tropolonato Complex Containing Photosensiti1

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“…It was subsequently found that complexes 19 reacted with tropolone to afford cationic molybdocene and tungstenocene complexes containing tropolonato ligand (C 7 H 5 O 2 − , trop) [47]. Tropolonato ligand, which is known to form a series of chelate complexes with metal ions, is the seven-membered ring analogue of the benzenoid catecholato ligand [48].…”

Section: Reactions Of the Di-μ-hydroxo Dinuclear Complexes With Tropomentioning

confidence: 99%

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Molybdocenes and tungstenocenes derived from molybdenum(IV) and tungsten(IV) dihydride

Minato

Ito

2008

Coordination Chemistry Reviews

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Section: Reactions Of the Di-μ-hydroxo Dinuclear Complexes With Tropomentioning

confidence: 99%

“…The calixarene-tropolonato ligand 24 was obtained in three steps from 4-tert-butyl-calix [4]arene (Scheme 10) [47]. The reaction of 24 with 19a proceeded in similar fashion as tropolone and resulted in the formation of the desired compound 25.…”

Section: Synthesis Of the Tropolonato Complex Containing Photosensitimentioning

confidence: 99%