“…As is well known, nanostructured materials with well-controlled shapes, sizes, crystalline phase, and structures play a critical role in determining the performance of LIBs. Various Zn x Co 3-x O 4 micro or nanostructures including sheets [1], particles [10,15], hierarchical nanostructure [16], hollow structures [9,17], Yolk-shell [18], wires [19], rods [20], tubes [21], nanoflakes [22] and porous structure [23] have been prepared by physical and chemical methods. Of particular interest is one dimensional structures such as rods or wires, which can provide efficient electrical transport pathway.…”