Synthesis of nano-sized ZnCo 2 O 4 anchored with graphene nanosheets as an anode material for secondary lithium ion batteries

Kumar, Alok; Thi, Trang Vu; Paul, Baboo Joseph; Kim, Jaekook

doi:10.1016/j.electacta.2014.09.079

Cited by 68 publications

(62 citation statements)

References 25 publications

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“…The reduction peak at 0.7 and 0.6 V in the cathodic process can be assigned to the reduction of ZnCo 2 O 4 to Zn and Co as described in Equation (1). The peak at 0.2 V may be due to the further lithiation of Zn to form a LieZn alloy as described in Equation (2) and the irreversible reaction related to the decomposition of the organic electrolyte to form a solid electrolyte interphase (SEI) layer [16]. This SEI layer plays a major role in the irreversible capacity loss and obstructs the movement of lithium ions.…”

Section: Electrochemical Performancementioning

confidence: 99%

Facile synthesis of mesoporous ZnCo2O4 coated with polypyrrole as an anode material for lithium-ion batteries

Zhong

Wang

Yang

et al. 2015

Journal of Power Sources

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Section: Electrochemical Performancementioning

confidence: 99%

Facile synthesis of mesoporous ZnCo2O4 coated with polypyrrole as an anode material for lithium-ion batteries

Zhong

Wang

Yang

et al. 2015

Journal of Power Sources

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“…A large number of new graphene-containing hybrids was also tested for the fi rst time (see Table 2 ) as LIB anode active materials (e.g., graphene-containing cobaltites, [291][292][293] carbonates, [ 294,295 ] sulfi des, [ 296,297 ] nitrides, [298][299][300][301] [ 309 ] Sb, [ 310 ] Sn-In, [ 311 ] In 2 O 3 , [ 312 ] Co 2 (OH) 3 Cl, [ 313 ] LiVPO 4 F, [ 314 ] V 2 O 3 [ 315 ] and V 2 O 5 [ 316 ] hybrids) but, unfortunately, none could entirely fulfi l the requirements of the ideal anode material for LIBs, although two hybrids [ 291,303 ] displayed a promisingly low 1 st cycle irreversible capacity (i.e., <20%).…”

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confidence: 99%

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

et al. 2016

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that its extraordinary properties would enable revolutionary new technologies, which gave birth to the "graphene era". [ 3,4 ] Relying on this scenario, in 2013, the European Union launched the ¤1 billion "Graphene Flagship" project aimed to investigate the properties of this new form of carbon for various applications (e.g., electronics, sensors and energy storage devices), with the ambitious goal of guiding graphene from laboratories to commercial applications within a decade. [ 5,6 ] In the same period, the Chinese Government set up a similar investment to mass-produce graphene as thin fi lms (e.g., for touchscreen electrodes) and platelets (e.g., for use in batteries). [ 6 ] In the following years, hundreds of patents, mainly focused on manufacturing and application in energy storage, were fi led and the worldwide production of graphene and graphene-containing materials rapidly increased. Although a few Chinese industries claimed to already use graphene-containing materials for smartphone production, no revolutionary practical application relying on graphene has been yet developed. [ 6 ] Specifi cally with respect to the battery fi eld, a close analysis of the scientifi c literature reveals a struggle to meet the ambitious initial targets. A potential loss of focus from the fi nal application caused by hype and ease of publication on such a novel matter, together with the delivery of very misleading information [ 7,8 ] and erroneous statements [ 7 ] concerning the use of graphene in batteries are emerging as possible reasons of the ineffective graphene-era outburst. In this progress report, we do not focus on production and classifi cation of graphene and graphene-containing materials, which were already well reported in the past years. [ 3,[9][10][11] In contrast, due to the lack of an exhaustive analysis of the progression of the use of such materials in lithium-ion battery (LIB) anodes, we report here a critical evaluation of the most prominent research papers published from 2008 until the end of 2015. As shown in Figure 1 , three different stages of the graphene research in LIB anodes can be distinguished: a fi rst stationary phase between 2008 and 2010 where the lithium-ion storage properties of different graphene and graphene-containing materials were preliminarily explored, a second exponential stage, spanning from 2010 to 2014, where graphene and graphene-containing anode materials were broadly developed and investigated, and fi nally, a third phase, (i.e., starting from 2015), where the research seems to have approached a plateau. After Used as a bare active material or component in hybrids, graphene has been the subject of numerous studies in recent years. Indeed, from the fi rst report that appeared in late July 2008, almost 1600 papers were published as of the end 2015 that investigated the properties of graphene as an anode material for lithium-ion batteries. Although an impressive amount of data has been collected, a real advance in the fi eld still seems to be missing. In this framework, atten...

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“…A C C E P T E D ACCEPTED MANUSCRIPT 4 Among the different nanostructured mixed-metal oxides, ZnCo 2 O 4 is considered a promising electrode material because of its advantages, including high theoretical capacity, improved reversible capacities, enhanced cycling stability, environmental friendliness, lower cost, and high thermal stability [10][11][12][13][14][15]. In addition, both Zn and Co are electrochemically active metals with respect to Li-metal.…”

Section: A N U S C R I P Tmentioning

confidence: 99%

High reversible capacity and rate capability of ZnCo 2 O 4 /graphene nanocomposite anode for high performance lithium ion batteries

Kumar

Kim

2015

Solid State Sciences

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Synthesis of nano-sized ZnCo 2 O 4 anchored with graphene nanosheets as an anode material for secondary lithium ion batteries

Cited by 68 publications

References 25 publications

Facile synthesis of mesoporous ZnCo2O4 coated with polypyrrole as an anode material for lithium-ion batteries

Facile synthesis of mesoporous ZnCo2O4 coated with polypyrrole as an anode material for lithium-ion batteries

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

High reversible capacity and rate capability of ZnCo 2 O 4 /graphene nanocomposite anode for high performance lithium ion batteries

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