Synthesis of (Ni1 − x Co x )2P (0 ≤ x ≤ 0.65) substitution solid solution

Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives

“…Phase evolution of Cr–B (CrB and CrB 2 phases), Mo–B (MoB 2 and Mo 2 B 5 phases), Co–P alloys, Ni–P alloys, Ni 70 P 30 (main phases: Ni 2 P and Ni 12 P 5 ), and Fe 8 P , (main phase: Fe 2 P) was investigated by reactive ball milling, a solid state method that avoids the loss of P/B or M in the solvent or in the gas phase. These results at the bulk scale were oriented by the imposed stoichiometry and by thermodynamics, which predicts that some particular phases are more stable than others. , (M x M′ 1‑ x )B 2 (M, M′ = Ti, Hf, Zr, Ta, Nb) and (Ni x Co 1‑ x ) 2 P solid solutions were also obtained. In the latter case, a phase segregation was observed for high Co proportions.…”

“…772 Moreover, dry autoclaving methods provided easy access to metal phosphide nanopowders. 34,773 InP polydisperse nanoparticles were also obtained by laser ablation of bulk InP in an aqueous environment. 774 The coupling of a gas-phase plasma synthesis and a colloidal step yielded InP−ZnS nanoparticles with good luminescence yield (15%).…”

“…It also led to MoP supported on carbon . Moreover, dry autoclaving methods provided easy access to metal phosphide nanopowders. , …”