2004
DOI: 10.1002/ejoc.200400429
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Synthesis of Novel Functionalized Polymers for the Diastereoselective Protonation of Chiral Enolates

Abstract: The polymeric, chelating proton donors 7 and 8 were synthesized by radical polymerization of the monomers 5/6 with different amounts of styrene. Protonation of chiral lithium enolates derived from silyl enol ethers 9 gave cis/trans ratios of up to 94:6 (10a) and 99:1 (10b), respectively. The polymers

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