2021
DOI: 10.1002/ejic.202100765
|View full text |Cite
|
Sign up to set email alerts
|

Synthesis of Novel Pseudocloso Ruthenacarboranes based on an Unsubstituted nido‐C2B9H112− Ligand

Abstract: The reaction of the known closo-ruthenacarborane 3-H-3-Cl-3,3-(PPh 3 ) 2 -closo-3,1,2-RuC 2 B 9 H 11 with tridentade nitrogen-based ligands of the general formula (C 5 NH 4 CH 2 ) 2 NR (R=H, Me, Et, iPr, Bu t ) in benzene solution at 60 °C allowed us to isolate novel ruthenacarborane clusters 3,3,3-(2'-NC 5 H 4 CH 2 ) 2 NR-pseudocloso-3,1,2-RuC 2 B 9 H 11 . According to the performed X-ray study, the obtained compounds are the first examples of pseudoclosometallacarboranes bearing unsubstituted C 2 B 9 2À nido… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2023
2023
2023
2023

Publication Types

Select...
3

Relationship

1
2

Authors

Journals

citations
Cited by 3 publications
(1 citation statement)
references
References 51 publications
0
1
0
Order By: Relevance
“…Ruthenacarboranes 11a-11e exhibit 18-e species and contain tridentate nitrogen-based ligands in their structure. Another peculiarity of the mentioned compounds is a so-called pseudocloso conformation of carborane ligand with enlarged C-C distance exceeding the sum of covalent radii [35]. These compounds are capable of reversible reduction at potentials close to E 1/2 of the Fc|Fc + couple.…”
Section: Resultsmentioning
confidence: 99%
“…Ruthenacarboranes 11a-11e exhibit 18-e species and contain tridentate nitrogen-based ligands in their structure. Another peculiarity of the mentioned compounds is a so-called pseudocloso conformation of carborane ligand with enlarged C-C distance exceeding the sum of covalent radii [35]. These compounds are capable of reversible reduction at potentials close to E 1/2 of the Fc|Fc + couple.…”
Section: Resultsmentioning
confidence: 99%