2024
DOI: 10.3390/molecules29184487
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Synthesis of Novel Planar-Chiral Charge-Compensated nido-Carborane-Based Amino Acid

Dmitry A. Gruzdev,
Angelina A. Telegina,
Marina A. Ezhikova
et al.

Abstract: Amino acids with unusual types of chirality and their derivatives have recently attracted attention as precursors in the synthesis of chiral catalysts and peptide analogues with unique properties. In this study, we have synthesized a new nido-carborane-based planar-chiral amino acid, in the molecule of which the amino group is directly bonded to the B(3) atom, and the carboxyl group is attached to the B(9) atom through the CH2S+(Me) fragment. 3-Amino-9-dimethylsulfonio-nido-carborane, prepared in three steps f… Show more

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