Synthesis of Novel Zwitterionic Surfactants: Achieving Enhanced Water Resistance and Adhesion in Emulsion Polymer Adhesives

Abstract

Recent advancements in polymer materials have enabled the synthesis of bio-based monomers from renewable resources, promoting sustainable alternatives to fossil-based materials. This study presents a novel zwitterionic surfactant, SF, derived from 10-undecenoic acid obtained from castor oil through a four-step reaction, achieving a yield of 78%. SF has a critical micelle concentration (CMC) of 1235 mg/L, slightly higher than the commercial anionic surfactant Rhodacal DS-4 (sodium dodecyl benzene sulfonate), and effectively stabilizes monomer droplets, leading to excellent conversion and stable latex formation. The zwitterionic groups in SF enhance adhesion to hydrophilic substrates (glass, stainless steel, and skin). Films produced with SF exhibit outstanding water resistance, with only 18.48% water uptake after 1800 min, compared to 81% for the control using Rhodacal DS-4. Notably, SF maintains low water uptake across various concentrations, minimizing water penetration. Thus, the synthesized SF demonstrates improved adhesive properties and excellent water resistance in emulsion polymerization applications, highlighting its potential as a sustainable, high-performance alternative to petrochemical surfactants.