Synthesis of P-stereogenic BINAP bissulfide analogues

Rafter, Eoin; Muldoon, Jimmy; Bunz, Helge Müller; Gilheany, Declan G.

doi:10.1016/j.tetasy.2011.09.007

Cited by 8 publications

(2 citation statements)

References 39 publications

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“…In addition, Wills and co-workers reported that, in some cases, the addition of zinc dust improves the yield [27]. Several research groups have adopted the Ni-catalyzed cross-coupling protocol developed by Cai et al for the synthesis of a wide variety of chiral phosphanes: axially chiral Quinazolinap ligand [28,29], P-stereogenic BINAP [30] and other binaphthyl-based phosphane and phosphite ligands [31]. Figure 9 shows selected examples, such as steroidal [32] and pyrazinylnaphthyl derivatives of BINAP [33], PINAPs [34,35], or fluoroalkyl-tagged binaphthyls [36,37].…”

Section: Arylation and Vinylation Of Secondary And Primary Phosphanesmentioning

confidence: 99%

Nickel Complexes in C‒P Bond Formation

et al. 2021

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This review is a comprehensive account of reactions with the participation of nickel complexes that result in the formation of carbon–phosphorus (C‒P) bonds. The catalytic and non-catalytic reactions with the participation of nickel complexes as the catalysts and the reagents are described. The various classes of starting compounds and the products formed are discussed individually. The several putative mechanisms of the nickel catalysed reactions are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this phosphorus chemistry.

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Section: Arylation and Vinylation Of Secondary And Primary Phosphanesmentioning

confidence: 99%

Nickel Complexes in C‒P Bond Formation

et al. 2021

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“…Chiral phosphines and derivatives can also be made via the coupling with chiral Csp 2 -O compounds with racemic phosphines followed by resolution (Scheme 1.58) and via the direct coupling with chiral P-H species (Scheme 1.59). [207][208][209] Scheme Metal-catalysed Csp 2 -B/P-H and Csp 2 -Bi/P−H cross couplings were reported recently. [210][211][212][213] Csp 2 -N/P-H cross-coupling of arylhydrazines and arldoazonium salts with Hphosphonates were also published recently.…”

Section: General Metal-catalysed C-x/p-y Cross-couplingsmentioning

confidence: 99%

Developing a new phosphorus-carbon bond synthesis

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Acknowledgement Firstly, I would like to thank my supervisor, Professor Francois Mathey, for his patience, kind guidance and sharing of knowledge. The journey would be much harder without his help. I also like to thank all the Professors and teachers who have taught me throughout my schooling years, particularly the chemistry teachers in my Secondary school and Junior College who teach the subject with so much enthusiasm. Secondly, I would like to thank my undergraduate mentor, Dr Tian Rongqiang for his mentorship and training. He has taught me many lab-related skills and we had great times

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