In this work, a unique reduced graphene oxide modified metallic cobalt (rGO/Co) composite, in which Co nanoparticles in situ anchored on rGO sheets, had been synthesized via a facile one pot co-precipitation approach. Such a composite exhibited an impressive performance when used in (asymmetric) supercapacitors. For comparison purposes, pure rGO and Co were also prepared and investigated. Microscopic observation techniques, nitrogen sorption analysis and electrochemical methods et al. were 10 used to characterize the materials' properties. The physical characterizations revealed rGO/Co possessed a "particle on sheet" structure with a "point to face" electronic contact between these two components, and the size of Co was much smaller than pure Co due to the geometric confinement of rGO, as well as a larger Brunauer-Emmett-Teller (BET) surface area resulted from the structure synergistic effect for alleviating the agglomeration of each component. Remarkably, the rGO/Co composite displayed the best 15 electrochemical performances among the three synthesized samples with the capacity as high as 882.7 F·g -1 at a current density of 2 A·g -1 and presented a high rate capability as well. Moreover, a asymmetric supercapacitor using rGO/Co as positive active materiel and activated carbon (AC) as negative active materiel has also been fabricated and tested in the potential window ranged between 0-1.6 V, which had been demonstrated could achieve a maximum energy density of 40.7 Wh·kg -1 at a power density of 20 1585.0 W·kg -1 as well as excellent rate capability and outstanding cycling durability. 65 Among various carbonaceous materials, graphene, a rising star, has attracted many attentions because of its extraordinary electrical stability, large surface area, superior mechanical properties, and good electrochemical stability. [23][24][25][26] Nevertheless, on the one hand, the previous reported research of such kind of 70 composites were in generl in a symmetric capacitor system resulted in a limited improvement in energy density; on the other The prepared rGO/Co//AC asymmetric supercapacitor displayed good electrochemical performances, which achieved a maximum energy density of 40.7 Wh·kg -1 at a power density of 1585.0 W·kg -1 .