2004
DOI: 10.1002/pola.20105
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Synthesis of pH‐sensitive surfactants by the terpolymerization of methacrylic acid, methoxy poly(ethylene glycol) methacrylate, and lauryl methacrylate: Initiator effect and reactivity ratio study

Abstract: For the development of pH‐sensitive surfactants to be used in water‐in‐oil fermentation, the free‐radical terpolymerization of methacrylic acid (MAA), methoxy poly(ethylene glycol) methacrylate (MPEGMA), and lauryl methacrylate (LMA), at a molar ratio of 1.0:0.04:0.76, was studied with two initiators, azobisisobutyronitrile (AIBN) and hydrogen peroxide, at different concentrations. The polymer synthesized with 0.45% AIBN as the initiator was the most promising, giving similar conversions of all three monomers … Show more

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