Synthesis of phosphonate-containing compounds

Hajinasiri, Rahimeh

doi:10.1016/j.tet.2023.133708

Tetrahedron

2023

DOI: 10.1016/j.tet.2023.133708

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Synthesis of phosphonate-containing compounds

Rahimeh Hajinasiri

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2024

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Asymmetric Conjugate Addition of Phosphine Sulfides to α-Substituted β-Nitroacrylates Using Cinchona Alkaloid Amide Catalysts

Miyake,

Iwamura,

Fujita

et al. 2024

Org. Lett.

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Chiral phosphine-containing amino acids are useful motifs in pharmaceutical compounds. In this study, we developed the asymmetric conjugate addition of phosphine sulfides with αsubstituted β-nitroacrylates to synthesize phosphine-containing amino acid precursors with chiral tetrasubstituted carbon centers. This method showed a wide substrate scope, and the obtained products were converted into various chiral compounds. The origin of the enantioselectivity was clarified by computational analysis.

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Asymmetric Conjugate Addition of Phosphine Sulfides to α-Substituted β-Nitroacrylates Using Cinchona Alkaloid Amide Catalysts

Miyake,

Iwamura,

Fujita

et al. 2024

Org. Lett.

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Synthesis of phosphonate-containing compounds

Cited by 1 publication

References 125 publications

Asymmetric Conjugate Addition of Phosphine Sulfides to α-Substituted β-Nitroacrylates Using Cinchona Alkaloid Amide Catalysts

Asymmetric Conjugate Addition of Phosphine Sulfides to α-Substituted β-Nitroacrylates Using Cinchona Alkaloid Amide Catalysts

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