Synthesis of Polymers Containing Group 15 Elements

Orthaber, Andreas; Soto, Alejandro Presa

doi:10.1002/9783527819140.ch4

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Heterocyclic Monomers1

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2019

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“…The ROP of cyclic phosphorus monomers is attractive, as the phosphorus ancillary unit enables easy functionalization and tuning of physical properties over a massive range (Scheme ). ,− Among the possible ancillary units, the phosphoesters are by far the most popular. The recent development of organocatalyzed ROP has been applied to phosphoesters with DBU, TBD, DBU/TU, and NHCs, providing well-controlled polymerizations. − The implementation of organocatalyzed ROP has enabled the recent exploration of polyphosphonates, polyphostones, and thionophosphoester, providing more hydrolysis, thermal, and photostable materials from less toxic starting materials. − …”

Section: Heterocyclic Monomersmentioning

confidence: 99%

Recent Trends in Catalytic Polymerizations

et al. 2019

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Polymers have become one of the largest and most important materials we use in daily life. Their popularity has stemmed from their wide range of material properties combined with their low cost of production. Both of these attractive traits have in part been enabled by the development of catalytic polymerizations, which provide both high levels of control while also delivering high levels of productivity. In this Perspective, we highlight recent trends and achievements made in the growing field of catalytic polymerizations.

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