Synthesis of potassium-incorporated caged-ladder-like polyhedral oligomeric silsesquioxane hybrid macromolecules for unique thermal intumescent properties and thermal decomposition studies

Qiao, Liang; Zhang, Wenchao; Yang, Rongjie

doi:10.1016/j.eurpolymj.2024.113027

European Polymer Journal

2024

DOI: 10.1016/j.eurpolymj.2024.113027

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Synthesis of potassium-incorporated caged-ladder-like polyhedral oligomeric silsesquioxane hybrid macromolecules for unique thermal intumescent properties and thermal decomposition studies

Liang Qiao,

Wenchao Zhang,

Rongjie Yang

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Cited by 4 publications

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Cu₁₂-Methylsilsesquioxane Cage Decorated with Cu(dppe)₂ Moieties for Mild Oxidative Functionalization of Alkanes

Bilyachenko,

Khrustalev,

Arteev

et al. 2024

Inorg. Chem.

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We report a high nuclear (Cu 14 ) complex synthesized via the self-assembly of copper-methylsilsesquioxane induced by the complexation with 1,2-bis(diphenylphosphino)ethane (dppe). The structure includes two cationic Cu I (dppe) 2 moieties and an anionic silsesquioxane cage of an unprecedented Cu II 12 structural type. The Cu 12 cage fragment exhibits a unique (i) combination of Si 4 -cyclic/Si 2 -acyclic silsesquioxane ligands and (ii) encapsulation of two different chloride and carbonate species. This complex acts as a promising precatalyst in the mild oxidation and carboxylation of light alkanes to produce alkyl hydroperoxides, alcohols, ketones, or carboxylic acids. The present study widens the family of copper-methylsilsesquioxane clusters with prospective use in oxidation catalysis.

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Cu₁₂-Methylsilsesquioxane Cage Decorated with Cu(dppe)₂ Moieties for Mild Oxidative Functionalization of Alkanes

Bilyachenko,

Khrustalev,

Arteev

et al. 2024

Inorg. Chem.

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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Bilyachenko,

Khrustalev,

Huang

et al. 2024

Dalton Trans.

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Rational (supra)molecular design and catalytic activity of cage-like Cu₄-based phenylsilsesquioxanes

Zueva,

Bilyachenko,

Khrustalev

et al. 2024

Nanoscale

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Synthesis of potassium-incorporated caged-ladder-like polyhedral oligomeric silsesquioxane hybrid macromolecules for unique thermal intumescent properties and thermal decomposition studies

Cited by 4 publications

References 44 publications

Cu₁₂-Methylsilsesquioxane Cage Decorated with Cu(dppe)₂ Moieties for Mild Oxidative Functionalization of Alkanes

Cu₁₂-Methylsilsesquioxane Cage Decorated with Cu(dppe)₂ Moieties for Mild Oxidative Functionalization of Alkanes

An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Rational (supra)molecular design and catalytic activity of cage-like Cu₄-based phenylsilsesquioxanes

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Synthesis of potassium-incorporated caged-ladder-like polyhedral oligomeric silsesquioxane hybrid macromolecules for unique thermal intumescent properties and thermal decomposition studies

Cited by 4 publications

References 44 publications

Cu12-Methylsilsesquioxane Cage Decorated with Cu(dppe)2 Moieties for Mild Oxidative Functionalization of Alkanes

Cu12-Methylsilsesquioxane Cage Decorated with Cu(dppe)2 Moieties for Mild Oxidative Functionalization of Alkanes

An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Rational (supra)molecular design and catalytic activity of cage-like Cu4-based phenylsilsesquioxanes

Contact Info

Product

Resources

About

Cu₁₂-Methylsilsesquioxane Cage Decorated with Cu(dppe)₂ Moieties for Mild Oxidative Functionalization of Alkanes

Cu₁₂-Methylsilsesquioxane Cage Decorated with Cu(dppe)₂ Moieties for Mild Oxidative Functionalization of Alkanes

Rational (supra)molecular design and catalytic activity of cage-like Cu₄-based phenylsilsesquioxanes