Synthesis of saturated bicyclic diesters

Mamedov, M. K.; Kadyrly, V. S.

doi:10.1134/s1070363217060056

Search citation statements

Order By: Relevance

Paper Sections

Select...

Introduction1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2020

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

(1 citation statement)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Cyclopentadiene, as a highly chemically active alicyclic hydrocarbon, which is generated undergoing normal Diels‐Alder addition reactions with unsaturated esters to form bicyclic esters, with a dicyclopentadiene (DCPD) as side product. Bicyclic ester is an important fine chemical intermediate which is commonly used in polymer plasticizers and lubricant additives …”

Section: Introductionmentioning

confidence: 99%

Synthesis of Bicyclic Esters in a Continuous‐Flow Microreactor

et al. 2020

View full text Add to dashboard Cite

The continuous-flow microreactor technique for the synthesis of bicyclic esters is reported in this paper. The synthesis time of bicyclic esters can be greatly shortened by the continuous-flow technique, and the advantage of continuous-flow microreactor is analyzed theoretically. Taking the synthesis of bicyclo[2,2,1]-5-hepten-2-methyl ester as an example, the molar ratio between cyclopentadiene (A) and methyl acrylate (B) is 1.1 to 1, the temperature is 353 K, the reaction time is 335 s, the yield reached 96.7% in a continuous-flow microreactor. However, it takes 4.5 hours to synthesize the compound within batch reaction, and the yield is 93%. It is of significant to change the batch reaction into continuous production both in the laboratory and industrial production.

show abstract

Section: Introductionmentioning

confidence: 99%