Synthesis of sodium (oxalate) difluoro borate-based hybrid electrolyte salts with enhanced interfacial properties for NaNi0.3Fe0.4Mn0.3O2 cathodes

Zhang, Jia; Li, Jianwei; Jia, Guofeng; Wang, Huaiyou; Wang, Min

doi:10.1039/d4se00118d

Sustainable Energy Fuels

2024

DOI: 10.1039/d4se00118d

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Synthesis of sodium (oxalate) difluoro borate-based hybrid electrolyte salts with enhanced interfacial properties for NaNi_0.3Fe_0.4Mn_0.3O₂ cathodes

Jia Zhang,

Jianwei Li,

Guofeng Jia

et al.

Abstract: Sodium difluoro-oxalate borate (NaODFB) stands out as a highly promising sodium salt and an influential additive in sodium-ion battery electrolytes. However, the impediments associated with the prevailing synthesis methodology, notably...

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Cited by 3 publications

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Electrolyte Design Strategies to Construct Stable Cathode‐Electrolyte Interphases for High‐Voltage Sodium‐Ion Batteries

Xie,

Ji,

Yang

et al. 2025

Advanced Energy Materials

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Elevating the working voltage of sodium‐ion batteries is crucial for expanding their application scenarios. However, as the operating voltage of these batteries increases, the interfacial stability of existing electrolytes becomes inadequate to meet the demands of high‐voltage cathode materials. Along with the interaction with cathode interface, electrolyte trends to be decomposed forming an interphase between the cathode and electrolyte, which plays an essential role in the performance of batteries. This review systematically focuses on the reconstruction of cathode‐electrolyte interphase maintaining the interfacial stability via various strategies at high voltage range. The state‐of‐the‐art characterization techniques and modeling approaches associated with cathode‐electrolyte interphase are also discussed. From the perspective of electrolyte design, the interphase reconstruction strategies focus on solvent molecule manipulation, solute ion manipulation, and the regulation of solvation‐ion interaction. By summarizing strategies for constructing a stable CEI on the cathode, this review aims to provide new insights into achieving high‐voltage sodium‐ion batteries.

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Electrolyte Design Strategies to Construct Stable Cathode‐Electrolyte Interphases for High‐Voltage Sodium‐Ion Batteries

Xie,

Ji,

Yang

et al. 2025

Advanced Energy Materials

View full text Add to dashboard Cite

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Improving Na3V2(PO4)2F3 half-cell performance with NaBF4-enhanced sodium difluoro(oxalato)borate electrolyte

Zhang,

Li,

Jia

et al. 2025

Journal of Energy Chemistry

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Construction of a stable interface at the Na_0.67Ni_0.33Mn_0.67O₂ cathode using LiDFOB electrolyte additives for high-performance sodium-ion batteries

Li,

Xu,

Zhu

et al. 2024

J. Mater. Chem. A

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Synthesis of sodium (oxalate) difluoro borate-based hybrid electrolyte salts with enhanced interfacial properties for NaNi_0.3Fe_0.4Mn_0.3O₂ cathodes

Abstract: Sodium difluoro-oxalate borate (NaODFB) stands out as a highly promising sodium salt and an influential additive in sodium-ion battery electrolytes. However, the impediments associated with the prevailing synthesis methodology, notably...

Cited by 3 publications

References 56 publications

Electrolyte Design Strategies to Construct Stable Cathode‐Electrolyte Interphases for High‐Voltage Sodium‐Ion Batteries

Electrolyte Design Strategies to Construct Stable Cathode‐Electrolyte Interphases for High‐Voltage Sodium‐Ion Batteries

Improving Na3V2(PO4)2F3 half-cell performance with NaBF4-enhanced sodium difluoro(oxalato)borate electrolyte

Construction of a stable interface at the Na_0.67Ni_0.33Mn_0.67O₂ cathode using LiDFOB electrolyte additives for high-performance sodium-ion batteries

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Synthesis of sodium (oxalate) difluoro borate-based hybrid electrolyte salts with enhanced interfacial properties for NaNi0.3Fe0.4Mn0.3O2 cathodes

Abstract: Sodium difluoro-oxalate borate (NaODFB) stands out as a highly promising sodium salt and an influential additive in sodium-ion battery electrolytes. However, the impediments associated with the prevailing synthesis methodology, notably...

Cited by 3 publications

References 56 publications

Electrolyte Design Strategies to Construct Stable Cathode‐Electrolyte Interphases for High‐Voltage Sodium‐Ion Batteries

Electrolyte Design Strategies to Construct Stable Cathode‐Electrolyte Interphases for High‐Voltage Sodium‐Ion Batteries

Improving Na3V2(PO4)2F3 half-cell performance with NaBF4-enhanced sodium difluoro(oxalato)borate electrolyte

Construction of a stable interface at the Na0.67Ni0.33Mn0.67O2 cathode using LiDFOB electrolyte additives for high-performance sodium-ion batteries

Contact Info

Product

Resources

About

Synthesis of sodium (oxalate) difluoro borate-based hybrid electrolyte salts with enhanced interfacial properties for NaNi_0.3Fe_0.4Mn_0.3O₂ cathodes

Construction of a stable interface at the Na_0.67Ni_0.33Mn_0.67O₂ cathode using LiDFOB electrolyte additives for high-performance sodium-ion batteries