Synthesis of Some Alkyl Acetates From Alcohols Catalyzed by H5PW10V2O40and H5PMo10V2O40Under Microwave Irradiation(Part 2)

Highly functionalized, high value added bioactive molecules are generally obtained by synthetic procedures that are highly selective, economical, with high atom economy, and environmentally friendly. Following these guidelines, the use of recoverable solid catalysts, nonpolluting substrates, or toxic organic solvent contributes greatly to these demands. In the last three decades, heteropolyacids (HPAs) and its derivatives have received great attention as recyclable solid catalysts, due to their strong Brönsted acidity, excellent oxidizing capacity under mild conditions, and various reuse cycles without appreciable loss of their catalytic activity. However, new activation methods should be investigated to improve the sustainability of a process using HPAs. In this review, we report the latest advances associated with the synthesis of potentially bioactive molecules using more energy efficient alternatives such as microwaves, ultrasound, mechanochemistry, and photochemistry to minimize the energy consumption associated with organic synthesis. The transformations studied include construction reaction, heterocycle synthesis, selective oxidation, and biomass recovery.

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Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis

Ruiz

Pasquale

Martínez

et al. 2022

Green Processing and Synthesis

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Synthesis of Some Alkyl Acetates From Alcohols Catalyzed by H₅PW₁₀V₂O₄₀and H₅PMo₁₀V₂O₄₀Under Microwave Irradiation(Part 2)

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Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis

Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis

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